•  

  • 46.
    Crystallographic and dielectric studies of tetrahedral {NH4@Fe4} crystallized with halomethane molecules
    CrystEngComm,25,4793-4797(2023)
    Daiki Matsumoto, Chiaki Tanaka, Masaru Fujibayashi, Sadafumi Nishihara,Kiyonori Takahashi, Takayoshi Nakamura, Tomoyuki Akutagawa, Atsuko Masuya-Suzuki and Ryo Tsunashima*
    Fron Cover Article

  • 45.
    Emergence of the super antenna effect in mixed crystals of ytterbium and lutetium complexes showing near-infrared luminescence
    RSC Adv., 12, 30598–30604 (2022)
    Atsuko Masuya-Suzuki,, Satoshi Gotob, Rika Nakamurab, Ryunosuke Karashimadab, Yasuhiro Kubotaogoc, Ryo Tsunashima and Nobuhiko Iki

  • 44.
    Slider-crank mechanism in a molecular crystal:conversion of linear thermal expansion of a lattice to circular rotation of a coordination chain
    CrystEngComm, 24, 5865-5869 (2022)Inside back cover
    R. Tsunashima, N. Fujikawa, M. Shiga, S. Miyagawa, S. Ohno, A. Masuya-Suzuki, T. Akutagawa, K. Takahashi, T. Nakamura, S. Nishihara



  • 43.
    Molecular solid solutions for advanced materials – homeomorphic or heteromorphic
    CrystEngComm, 24, 1309-1318 (2022),Review,Hot article collection,Inside back cover
    Ryo Tsunashima

  • 42.
    Structural Phase Transitions of a Molecular Metal Oxide
    Angew. Chem. Int. Ed., 2020, 59, 22446-22450 (2020).
    Masaru Fujibayashi, Yu Watari, Ryo Tsunashima,* Sadafumi Nishihara, Shin-ichiro Noro, Chang-Gen Lin, Yu-Fei Song, Kiyonori Takahashi, Takayoshi Nakamura, and Tomoyuki Akutagawa
    LINK
  • 41.
    Spin Crossover between the High-spin and Low-spin States and Dielectric Switching in the Ionic Crystals of a Fe(II) [2 × 2] Molecular Grid
    Bull. Chem. Soc. Jpn,2020, 93, 1583-1587 (2020),BCSJ Award Article,Cover Article.
    Yuta Uezu, Ryo Tsunashima,* Chiaki Tanaka, Masaru Fujibayashi, Jun Manabe, Sadafumi Nishihara and Katsuya Inoue
    LINK
  • 40.
    Doping of Metal-free Molecular Perovskite with Hexamethylenetetramine to Create Non-centrosymmetric Defects
    CrystEngComm, 2020, 22, 2279-2282 (Cover Picture&HOT articles)
    Hagino Morita, Ryo Tsunashima,* Sadafumi Nishihara and Tomoyuki Akutagawa

  • 39.
    Anisotropic Polyoxometalate Cages Assembled via Layers of Heteroanion Templates
    J. Am. Chem. Soc., 2019, 141, 13479-13486.

    Qi Zheng, Manuel Kupper, Weimin Xuan, Hirofumi Oki, Ryo Tsunashima, De-Liang Long* and Leroy Cronin*
  • 38.
    Ferroelectric Behavior of a Hexamethylenetetramine‐Based Molecular Perovskite Structure
    Angew. Chem. Int. Ed., 2019, 58, 9184-9187.
    Hagino Morita, Ryo Tsunashima,* Sadafumi Nishihara, Katsuya Inoue, Yuriko Omura, Yasutaka Suzuki, Jun Kawamata, Norihisa Hoshino, and Tomoyuki Akutagawa
  • 37.
    Synthesis, Structure, and Electrochemical Properties of [Na(SO3)2(RPO3)4MoV4MoVI14O49]5− (R = propyl or t-butyl)
    Bull. Chem. Soc. Jpn., 2019, 92, 918-922

    Masaru Fujibayashi, Misaki Shiga, Ryo Tsunashima*, Takayoshi Nakamura
  • 36.
    Structural Phase Transition Behavior Observed for a Single Crystal of the Tetrabutylammonium Salt of a Mo18 Polyoxometalate
    Eur. J. Inorg. Chem., 2019, 492-495.

    Hirofumi Oki, Misaki Shiga, Ippei Nakamura, Kazuki Nishida, Katsuya Ichihashi, Sadafumi Nishihara, Katsuya Inoue, Tomoyuki Akutagawa, and Ryo Tsunashima*
  • 35.
    Giant Hysteretic Single-Molecule Electric Polarisation Switching above Room Temperature
    Angew. Chem. Int. Ed., 2018, 57, 13429-13432. (Hot Article)

    C. Kato, R. Machida, R. Maruyama, R. Tsunashima, X.-M. Ren, M. Kurmoo, K. Inoue, and S. Nishihara*
  • 34.
    Chemo-chromism in an orthogonal dabco-based Co(II) network assembled by methanol-coordination and hydrogen bond formation
    Dalton Trans., 2018, 47, 7656-7662. (Back Cover)

    Misaki Shiga, Shogo Kawaguchi, Masaru Fujibayashi, Sadafumi Nishihara, Katsuya Inoue, Tomoyuki Akutagawa, Shin-ichiro Noro, Takayoshi Nakamura and Ryo Tsunashima*


  • 33.
    Inter-cluster distance dependence of electrical properties in single crystals of a mixed-valence polyoxometalate

    Dalton Trans., 2017, 46, 12619
    Ryo Tsunashima,* Ippei Nakamura, Rika Oue, Seiya Koga, Hirofumi Oki, Shin-ichiro Noro, Takayoshi Nakamura and Tomoyuki Akutagawa
  • 32.
    A dielectric anomaly observed for doubly reducedmixed-valence polyoxometalate

    Chem. Comm., 2017, 53, 6824-6827(Back cover)
    I. Nakamura, R. Tsunashima,* S. Nishihara, K. Inoue and T. Akutagawa
  • 31.
    Synthesis, Characterization, and Structure of a Reduced Preyssler-type Polyoxometalate

    Chem. Lett., 2017, 46, 602-604.

    C. Kato, K. Y. Maryunina, K. Inoue,* S. Yamaguchi, H. Miyaoka, A. Hayashi, M. Sadakane, R. Tsunashima, and S. Nishihara*
  • 30.
    Solid-state structure and electronic states of hydrogen-bonded dimer of pyridyl-substituted tetrathiafulvalene salted with PF6−

    RSC Adv., 2017, 7, 6236-6241

    Tomoaki Kanetou, Ryo Tsunashima*, Norihisa Hoshino and Tomoyuki Akutagawa
    DOI: 10.1039/C6RA27814K
  • 29.
    Solvent Triggered Transition of Electrical Conductivity of Polyoxomet-alate-Based Hybrid with Ni-Pyridyl-Tetrathiafulvalene

    Current Inorganic Chemistry, 2016, 7

    Yusuke Baba, Ryo Tsunashima*, Norihisa Hoshino, Tomoyuki Akutagawa, Shin-Ichiro Noro and Takayoshi Nakamura
  • 28.
    Exploring the solvent mediated assembly and redox activity of a POM–organic hybrid [Na(SO3)2(PhPO3)4MoV4MoVI14O49]5−
    New J. Chem., 2016, 40, 8488-8492

    Masaru Fujibayashi, Yu-Fei Song, Leroy Cronin and Ryo Tsunashima*
  • 27.
    Synthesis and acid–base properties of a proton-bridged biaryl compound based on pyridylazulene

    New J. Chem., 2015, 39, 9079-9085.(Cover picture)

    K. Ninomiya, Y, Harada, T. Kanetou, Y. Suenaga, T. Murafuji* and R. Tsunashima*
  • 26
    Large in-plane/out-of-plane anisotropic conduction in PEDOT-based hybrid films: Lamellar assemblies structured by mono-layered nano-sheets

    J. Mater. Chem. C, 2015, 3, 7153-7158.

    S. Fujii, Y. Suzuki, J. Kawamata* and R. Tsunashima*
  • 25
    Investigating the Formation of “Molybdenum Blues” with Gel Electrophoresis and Mass Spectrometry
    J. Am. Chem. Soc. 2015, 137, 6524-6530

    I. Nakamura, H. N. Miras, A. Fujiwara, M. Fujibayashi, Y.-F. Song, L. Cronin,* and R. Tsunashima*
  • 24
    Electrical Network of Single-Crystalline Metal Oxide Nanoclusters Wired by π-Molecules
    Angew. Chem. Int. Ed., 2014, 42, 11228-11231(inside back cover)

    R. Tsunashima,*Y. Iwamoto, Y. Baba, C. Kato, K. Ichihashi, S. Nishihara, K. Inoue, K. Ishiguro, Y.-F. Song, T. Akutagawa
  • 23
    Concentration Dependent Stability of Fullerene-shaped Metal-oxide Nanocluster {Mo132} in Aqueous Solution
    Sci. Adv. Mater., 2014, 6, 1389-1393

    T. Matsumoto, I. Nakamura, K. Ishiguro, R. Tsunashima*
  • 22
    Recent advances on polyoxometalates intercalated layered double hydroxides: From synthetic approaches to functional material applications
    Coord. Chem. Rev., 2014, 258-259, 58-71

    S.Omwoma, W. Chen, R. Tsunashima, Y.-F. Song*
  • 21
    Heterocyclic bismuth carboxylates based on a diphenyl sulfone scaffold: Synthesis and antifungal activity against Saccharomyces cerevisiae
    Eur. J. Med. Chem., 2013, 63, 531-535

    T. Murafuji,* K. Kitagawa, D. Yoshimatsu, K. Kondo, K. Ishiguro, R. Tsunashima, I. Miyakawa, Y. Mikata
  • 20.
    Quick and selective synthesis of Li6[a-P2W18O62]28H2O soluble in various organic solvents
    Dalton. Trans., 2013, 42, 11363-11366

    C. Kato, S. Nishihara,* R. Tsunashima, Y. Tatewaki, S. Okada, X.-M. Ren, K. Inoue,* D.-L. Long and L. Cronin
  • 19.
    Electrospun Self-Supporting Nanocomposite Films of Na9[EuW10O36]・32H2O/PAN as pH-Modulated Luminescent Switch
    Ind. Eng. Chem. Res, 2013, 52, 2598-2603

    X.Wang, J. Wang, R. Tsunashima, K. Pan,* B. Cao, and Y.-F. Song*
  • 18.
    Color-Tunable Luminescent Films Based on the Hybrid Assemblies of [EuW10O36]9-, Bis(N-methylacridinium) Nitrate, and Layered Double Hydroxide
    Eur. J. Inorg. Chem, 2013, 9, 1475-1480.

    Z. Han. Y. Guo, R. Tsunashima, Y.-F. Song*
  • 17.
    Recent advances on polyoxometalates-based molecular and composite materials
    Chem. Soc. Rev., 2012, 41, 7384-7402.　(cover picture)

    Y. F. Song* and R. Tsunashima*

  • 16.
    Incorporation of Cationic Electron Donor of Ni-pyridyl-tetrathiafulvalene with Anionic Electron Acceptor of Polyoxometalate
    Dalton. Trans., 2012, 41, 10060-10064

    R. Tsunashima,*T. Matsumoto, N. Hoshino, W. Niiho, M. Kimura, K. Kondo, Y. Suyama, Y. Nishioka, J. Kawamata, S.-i. Noro, T.Nakamura, T. Akutagawa, K. Ishiguro*
  • 15.
    Exploring the mobility of nanoscale polyoxometalates using gel electrophoresis
    Chem. Sci., 2012, 3, 343-348 (cover picture)

    R. Tsunashima, C. Richmond and L. Cronin*

  • 14.Insertion of Benzyne into a Bi-S Bond: A New Synthetic Route to ortho-Functionalized Bismuthanes and Its Application to the Synthesis of Dibenzothiophene
    Organometallics, 2011, 30, 4532-4538

    J. Chen, T. Murafuji,* R. Tsunashima
  • 13. Hydrogen-bonded Assemblies of Two-Electron Reduced Mixed-Valence [XMo12O40] (X = P and Si) with p-Phenylenediamines
    Inorg. Chem., 2011, 50, 6711-6718

    T. Akutagawa,* F. Kudo, R. Tsunashima, S.-i. Noro, L. Cronin,* T. Nakamura*
  • 12. Exploring the thermochromism of sulfite-embedded polyoxometalate capsules
    Phys. Chem. Chem. Phys., 2011, 13, 7295-7297

    R. Tsunashima, D.-L. Long, T. Endo, S.-i. Noro, T. Akutagawa, T. Nakamura, R. Q. Cabrera, P. F. McMillan, P. Kogerler, L. Cronin*
  • 11. Polyoxometalates: Building Blocks for Functional Nanoscale Systems
    Angew. Chem. Int. Ed., 2010, 49, 1736-1758(review paper)

    D.-L. Long, R. Tsunashima, L. Cronin*
  • 10. The Construction of High Nuclearity Isopolyoxoniobates With Pentagonal Building Blocks: [HNb27O76]16- and [H10Nb31O93(CO3)]23-
    Angew. Chem. Int. Ed., 2010, 49, 113-116

    R. Tsunashima, D.-L. Long, H. N. Miras, D. Gabb, C. P. Pradeep, L. Cronin*
  • 9. Adsorption and Catalytic Properties of the Inner 'Nanospace' of a Gigantic Ring-Shaped Polyoxometalate Cluster
    Angew. Chem. Int. Ed., 2009, 48, 8703-8706

    S. Noro,* R. Tsunashima, Y. Kamiya, K. Uemura, H. Kita, L. Cronin, T. Akutagawa, T. Nakamura*
  • 8. Conductive Nanoscopic Fibrous Assemblies Containing Helical Tetrathiafulvalene Stacks
    Chem. Asian J, 2009, 4, 1474-1479

    Y. Tatewaki, T. Hatanaka, R. Tsunashima, T. Nakamura, M. Kimura, H. Shirai
  • 7. Supramolecular Silver Polyoxometalate Architectures Direct the Growth of Composite Semiconducting Nanostructures
    Angew. Chem. Int. Ed., 2009, 48, 6490-6493.

    C. Streb, R. Tsunashima, D. A. MacLaren, T. McGlone, T. Akutagawa, T. Nakamura, A. Scandurra, B. Pignataro, N. Gadegaard, and L. Cronin*
  • 6. Electrical resistivity of individual molecular-assembly nanowires of amphiphilic bis-tetrathiafulvalene macrocycle/2,3,5,6-tetrafluoro- 7,7,8,8-tetracyano-p-quinodimethane charge transfer complex characterized by point-contact current-imaging atomic force microscopy
    Appl. Phys. Lett. 2008, 93, 1731021-17310213.

    R. Tsunashima, Y. Noda, Y. Tatewaki, S.-I. Noro, T. Akutagawa, T. Nakamura,* T. Matsumoto, T. Kawai
  • 5. Fullerene Nanowires: Self-Assembly Structures of a Low-Molecular-Weight Organogelator Fabricated by the Langmuir-Blodgett Method
    Chem. -Eur. J., 2008, 14, 8169-8170

    R. Tsunashima, S.-i. Noro, T. Akutagawa, T. Nakamura,* H. Kawakami, K. Toma
  • 4. Molecular-Assembly of Amphiphilic Gigantic {Mo154}-Ring: (Dimethyldioctadecylammoni um)20 [Mo154O462H+8(H2O)90]
    Langmuir, 2008, 24, 231-238

    T. Akutagawa, R. Jin, R. Tsunashima, S.-i. Noro, L. Cronin, T. Nakamura*
  • 3. Langmuir-Blodgett Films Constructed by Amphiphilic bis-TTF Annulated Macrocycle-2,3,5,6-Tetrafluoro-7,7,8,8-tetracyano-p-quinodimethane Charge Transfer Complex and Gold Nanoparticles
    J. Phys. Chem. C, 2007, 111, 18871-18877(cover picture)

    Y. Tatewaki, Y. Noda, T. Akutagawa, R. Tsunashima, S.-i. Noro, T. Nakamura, H. Hasegawa, S. Mashiko and J. Becher
  • 2. One-Dimensional Array of Au Nanoparticles Fixed on Nanofibers of Organogelators by the Langmuir-Blodgett Method
    J. Phys. Chem. C, 2007, 111, 901-907.

    R. Tsunashima, S.-i. Noro, T. Akutagawa, T. Nakamura,* T. Karasawa, H. Kawakami, and K. Toma
  • 1. Synthesis, Isolation, and Structural Characterization of C4h Isomer of Metal(1,2-naphthalocyanine) and Its One-Dimensional Conductor of Axially Substituted Species
    Inorg. Chem., 2006, 45, 4170-4176

    E. H. Gacho, H. Imai, R. Tsunashima, T, Naito, T. Inabe* and N. Kobayashi
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