• 50. Solvent-assisted mechanochemical crystallization of themetal-free perovskite solid solution (H2dabco, H2hmta)NH4(BF4)3
    Chem Commun,60,12181-12184 (2024)
    J. Moriguchi, T. Koga, N. Tsunoji, S. Nishihara, T. Akutagawa and R. Tsunashima*
    Inside Back Cover

  • 49.
    Manipulating the supramolecular assembly of γ-cyclodextrin and Anderson polyoxometalate hybrids through variations in remote functionality
    Cell Reports Physical Science, 5, 102061 (2024)
    Yi An Yin, Wu Ji Chen, Chun Yan Liu, Meng Meng Zhang, Chang Gen Lin, Ryo Tsunashima, Haralampos N. Miras, Yu Fei Song
  • 48.
    Effect of halide solid solution on the structure, phase transition behaviour and dielectric properties of dabcoH+ chains
    CrystEngComm, 26, 3468-3474 (2024)
    Yuki Ohishi, Kohei Sambe, Shun Dekura, Tomoyuki Akutagawa, Atsuko Masuya-Suzuki and Ryo Tsunashima*
    Front Cover Article

  • 47.
    Crystallographic and dielectric studies of tetrahedral {NH4@Fe4} crystallized with halomethane molecules
    CrystEngComm,25,4793-4797(2023)
    Daiki Matsumoto, Chiaki Tanaka, Masaru Fujibayashi, Sadafumi Nishihara,Kiyonori Takahashi, Takayoshi Nakamura, Tomoyuki Akutagawa, Atsuko Masuya-Suzuki and Ryo Tsunashima*
    Front Cover Article

  • 46.
    Emergence of the super antenna effect in mixed crystals of ytterbium and lutetium complexes showing near-infrared luminescence
    RSC Adv., 12, 30598–30604 (2022)
    Atsuko Masuya-Suzuki,, Satoshi Gotob, Rika Nakamurab, Ryunosuke Karashimadab, Yasuhiro Kubotaogoc, Ryo Tsunashima and Nobuhiko Iki

  • 45.
    Slider-crank mechanism in a molecular crystal:conversion of linear thermal expansion of a lattice to circular rotation of a coordination chain
    CrystEngComm, 24, 5865-5869 (2022)Inside back cover
    R. Tsunashima, N. Fujikawa, M. Shiga, S. Miyagawa, S. Ohno, A. Masuya-Suzuki, T. Akutagawa, K. Takahashi, T. Nakamura, S. Nishihara



  • 44.
    Molecular solid solutions for advanced materials – homeomorphic or heteromorphic
    CrystEngComm, 24, 1309-1318 (2022),Review,Hot article collection,Inside back cover
    Ryo Tsunashima

  • 43.
    Structural Phase Transitions of a Molecular Metal Oxide
    Angew. Chem. Int. Ed., 2020, 59, 22446-22450 (2020).
    Masaru Fujibayashi, Yu Watari, Ryo Tsunashima,* Sadafumi Nishihara, Shin-ichiro Noro, Chang-Gen Lin, Yu-Fei Song, Kiyonori Takahashi, Takayoshi Nakamura, and Tomoyuki Akutagawa
    LINK
  • 42.
    Gas-Dependent Reversible Structural and Magnetic Transformation between Two Ladder Compounds
    Crystals, 2020, 10, 841
    Jun Manabe Kazuki Nishida Xiao Zhang Yuki Nakano Masaru Fujibayashi Goulven Cosquer Katsuya Inoue Seiya Shimono Hiroki Ishibashi Yoshiki Kubota Misaki Shiga Ryo Tsunashima Yoko Tatewaki Sadafumi Nishihara
  • 41.
    Spin Crossover between the High-spin and Low-spin States and Dielectric Switching in the Ionic Crystals of a Fe(II) [2 × 2] Molecular Grid
    Bull. Chem. Soc. Jpn,2020, 93, 1583-1587 (2020),BCSJ Award Article,Cover Article.
    Yuta Uezu, Ryo Tsunashima,* Chiaki Tanaka, Masaru Fujibayashi, Jun Manabe, Sadafumi Nishihara and Katsuya Inoue
    LINK
  • 40.
    Doping of Metal-free Molecular Perovskite with Hexamethylenetetramine to Create Non-centrosymmetric Defects
    CrystEngComm, 2020, 22, 2279-2282 (Cover Picture&HOT articles)
    Hagino Morita, Ryo Tsunashima,* Sadafumi Nishihara and Tomoyuki Akutagawa

  • 39.
    Anisotropic Polyoxometalate Cages Assembled via Layers of Heteroanion Templates
    J. Am. Chem. Soc., 2019, 141, 13479-13486.

    Qi Zheng, Manuel Kupper, Weimin Xuan, Hirofumi Oki, Ryo Tsunashima, De-Liang Long* and Leroy Cronin*
  • 38.
    Ferroelectric Behavior of a Hexamethylenetetramine‐Based Molecular Perovskite Structure
    Angew. Chem. Int. Ed., 2019, 58, 9184-9187.

    Hagino Morita, Ryo Tsunashima,* Sadafumi Nishihara, Katsuya Inoue, Yuriko Omura, Yasutaka Suzuki, Jun Kawamata, Norihisa Hoshino, and Tomoyuki Akutagawa
  • 37.
    Synthesis, Structure, and Electrochemical Properties of [Na(SO3)2(RPO3)4MoV4MoVI14O49]5− (R = propyl or t-butyl)
    Bull. Chem. Soc. Jpn., 2019, 92, 918-922

    Masaru Fujibayashi, Misaki Shiga, Ryo Tsunashima*, Takayoshi Nakamura
  • 36.
    Structural Phase Transition Behavior Observed for a Single Crystal of the Tetrabutylammonium Salt of a Mo18 Polyoxometalate
    Eur. J. Inorg. Chem., 2019, 492-495.

    Hirofumi Oki, Misaki Shiga, Ippei Nakamura, Kazuki Nishida, Katsuya Ichihashi, Sadafumi Nishihara, Katsuya Inoue, Tomoyuki Akutagawa, and Ryo Tsunashima*
  • 35.
    Giant Hysteretic Single-Molecule Electric Polarisation Switching above Room Temperature
    Angew. Chem. Int. Ed., 2018, 57, 13429-13432. (Hot Article)

    C. Kato, R. Machida, R. Maruyama, R. Tsunashima, X.-M. Ren, M. Kurmoo, K. Inoue, and S. Nishihara*
  • 34.
    Chemo-chromism in an orthogonal dabco-based Co(II) network assembled by methanol-coordination and hydrogen bond formation
    Dalton Trans., 2018, 47, 7656-7662. (Back Cover)

    Misaki Shiga, Shogo Kawaguchi, Masaru Fujibayashi, Sadafumi Nishihara, Katsuya Inoue, Tomoyuki Akutagawa, Shin-ichiro Noro, Takayoshi Nakamura and Ryo Tsunashima*


  • 33.
    Inter-cluster distance dependence of electrical properties in single crystals of a mixed-valence polyoxometalate

    Dalton Trans., 2017, 46, 12619
    Ryo Tsunashima,* Ippei Nakamura, Rika Oue, Seiya Koga, Hirofumi Oki, Shin-ichiro Noro, Takayoshi Nakamura and Tomoyuki Akutagawa
  • 32.
    A dielectric anomaly observed for doubly reducedmixed-valence polyoxometalate

    Chem. Comm., 2017, 53, 6824-6827(Back cover)
    I. Nakamura, R. Tsunashima,* S. Nishihara, K. Inoue and T. Akutagawa
  • 31.
    Synthesis, Characterization, and Structure of a Reduced Preyssler-type Polyoxometalate
    Chem. Lett., 2017, 46, 602-604.
    C. Kato, K. Y. Maryunina, K. Inoue,* S. Yamaguchi, H. Miyaoka, A. Hayashi, M. Sadakane, R. Tsunashima, and S. Nishihara*
  • 30.
    Solid-state structure and electronic states of hydrogen-bonded dimer of pyridyl-substituted tetrathiafulvalene salted with PF6−
    RSC Adv., 2017, 7, 6236-6241
    Tomoaki Kanetou, Ryo Tsunashima*, Norihisa Hoshino and Tomoyuki Akutagawa
    DOI: 10.1039/C6RA27814K
  • 29.
    Solvent Triggered Transition of Electrical Conductivity of Polyoxomet-alate-Based Hybrid with Ni-Pyridyl-Tetrathiafulvalene
    Current Inorganic Chemistry, 2016, 7
    Yusuke Baba, Ryo Tsunashima*, Norihisa Hoshino, Tomoyuki Akutagawa, Shin-Ichiro Noro and Takayoshi Nakamura
  • 28.
    Exploring the solvent mediated assembly and redox activity of a POM–organic hybrid [Na(SO3)2(PhPO3)4MoV4MoVI14O49]5−
    New J. Chem., 2016, 40, 8488-8492

    Masaru Fujibayashi, Yu-Fei Song, Leroy Cronin and Ryo Tsunashima*
  • 27.
    Synthesis and acid–base properties of a proton-bridged biaryl compound based on pyridylazulene

    New J. Chem., 2015, 39, 9079-9085.(Cover picture)

    K. Ninomiya, Y, Harada, T. Kanetou, Y. Suenaga, T. Murafuji* and R. Tsunashima*
  • 26
    Large in-plane/out-of-plane anisotropic conduction in PEDOT-based hybrid films: Lamellar assemblies structured by mono-layered nano-sheets

    J. Mater. Chem. C, 2015, 3, 7153-7158.

    S. Fujii, Y. Suzuki, J. Kawamata* and R. Tsunashima*
  • 25
    Investigating the Formation of “Molybdenum Blues” with Gel Electrophoresis and Mass Spectrometry
    J. Am. Chem. Soc. 2015, 137, 6524-6530

    I. Nakamura, H. N. Miras, A. Fujiwara, M. Fujibayashi, Y.-F. Song, L. Cronin,* and R. Tsunashima*
  • 24
    Electrical Network of Single-Crystalline Metal Oxide Nanoclusters Wired by π-Molecules
    Angew. Chem. Int. Ed., 2014, 42, 11228-11231(inside back cover)

    R. Tsunashima,*Y. Iwamoto, Y. Baba, C. Kato, K. Ichihashi, S. Nishihara, K. Inoue, K. Ishiguro, Y.-F. Song, T. Akutagawa
  • 23
    Concentration Dependent Stability of Fullerene-shaped Metal-oxide Nanocluster {Mo132} in Aqueous Solution
    Sci. Adv. Mater., 2014, 6, 1389-1393
    T. Matsumoto, I. Nakamura, K. Ishiguro, R. Tsunashima*
  • 22
    Recent advances on polyoxometalates intercalated layered double hydroxides: From synthetic approaches to functional material applications
    Coord. Chem. Rev., 2014, 258-259, 58-71

    S.Omwoma, W. Chen, R. Tsunashima, Y.-F. Song*
  • 21
    Heterocyclic bismuth carboxylates based on a diphenyl sulfone scaffold: Synthesis and antifungal activity against Saccharomyces cerevisiae
    Eur. J. Med. Chem., 2013, 63, 531-535

    T. Murafuji,* K. Kitagawa, D. Yoshimatsu, K. Kondo, K. Ishiguro, R. Tsunashima, I. Miyakawa, Y. Mikata
  • 20.
    Quick and selective synthesis of Li6[a-P2W18O62]28H2O soluble in various organic solvents
    Dalton. Trans., 2013, 42, 11363-11366

    C. Kato, S. Nishihara,* R. Tsunashima, Y. Tatewaki, S. Okada, X.-M. Ren, K. Inoue,* D.-L. Long and L. Cronin
  • 19.
    Electrospun Self-Supporting Nanocomposite Films of Na9[EuW10O36]・32H2O/PAN as pH-Modulated Luminescent Switch
    Ind. Eng. Chem. Res, 2013, 52, 2598-2603

    X.Wang, J. Wang, R. Tsunashima, K. Pan,* B. Cao, and Y.-F. Song*
  • 18.
    Color-Tunable Luminescent Films Based on the Hybrid Assemblies of [EuW10O36]9-, Bis(N-methylacridinium) Nitrate, and Layered Double Hydroxide
    Eur. J. Inorg. Chem, 2013, 9, 1475-1480.
    Z. Han. Y. Guo, R. Tsunashima, Y.-F. Song*
  • 17.
    Recent advances on polyoxometalates-based molecular and composite materials
    Chem. Soc. Rev., 2012, 41, 7384-7402.　(cover picture)
    Y. F. Song* and R. Tsunashima*
  • 16.
    Incorporation of Cationic Electron Donor of Ni-pyridyl-tetrathiafulvalene with Anionic Electron Acceptor of Polyoxometalate
    Dalton. Trans., 2012, 41, 10060-10064
    R. Tsunashima,*T. Matsumoto, N. Hoshino, W. Niiho, M. Kimura, K. Kondo, Y. Suyama, Y. Nishioka, J. Kawamata, S.-i. Noro, T.Nakamura, T. Akutagawa, K. Ishiguro*
  • 15.
    Exploring the mobility of nanoscale polyoxometalates using gel electrophoresis
    Chem. Sci., 2012, 3, 343-348 (cover picture)
    R. Tsunashima, C. Richmond and L. Cronin*

  • 14.Insertion of Benzyne into a Bi-S Bond: A New Synthetic Route to ortho-Functionalized Bismuthanes and Its Application to the Synthesis of Dibenzothiophene
    Organometallics, 2011, 30, 4532-4538

    J. Chen, T. Murafuji,* R. Tsunashima
  • 13. Hydrogen-bonded Assemblies of Two-Electron Reduced Mixed-Valence [XMo12O40] (X = P and Si) with p-Phenylenediamines
    Inorg. Chem., 2011, 50, 6711-6718

    T. Akutagawa,* F. Kudo, R. Tsunashima, S.-i. Noro, L. Cronin,* T. Nakamura*
  • 12. Exploring the thermochromism of sulfite-embedded polyoxometalate capsules
    Phys. Chem. Chem. Phys., 2011, 13, 7295-7297

    R. Tsunashima, D.-L. Long, T. Endo, S.-i. Noro, T. Akutagawa, T. Nakamura, R. Q. Cabrera, P. F. McMillan, P. Kogerler, L. Cronin*
  • 11. Polyoxometalates: Building Blocks for Functional Nanoscale Systems
    Angew. Chem. Int. Ed., 2010, 49, 1736-1758(review paper)

    D.-L. Long, R. Tsunashima, L. Cronin*
  • 10. The Construction of High Nuclearity Isopolyoxoniobates With Pentagonal Building Blocks: [HNb27O76]16- and [H10Nb31O93(CO3)]23-
    Angew. Chem. Int. Ed., 2010, 49, 113-116

    R. Tsunashima, D.-L. Long, H. N. Miras, D. Gabb, C. P. Pradeep, L. Cronin*
  • 9. Adsorption and Catalytic Properties of the Inner 'Nanospace' of a Gigantic Ring-Shaped Polyoxometalate Cluster
    Angew. Chem. Int. Ed., 2009, 48, 8703-8706

    S. Noro,* R. Tsunashima, Y. Kamiya, K. Uemura, H. Kita, L. Cronin, T. Akutagawa, T. Nakamura*
  • 8. Conductive Nanoscopic Fibrous Assemblies Containing Helical Tetrathiafulvalene Stacks
    Chem. Asian J, 2009, 4, 1474-1479

    Y. Tatewaki, T. Hatanaka, R. Tsunashima, T. Nakamura, M. Kimura, H. Shirai
  • 7. Supramolecular Silver Polyoxometalate Architectures Direct the Growth of Composite Semiconducting Nanostructures
    Angew. Chem. Int. Ed., 2009, 48, 6490-6493.

    C. Streb, R. Tsunashima, D. A. MacLaren, T. McGlone, T. Akutagawa, T. Nakamura, A. Scandurra, B. Pignataro, N. Gadegaard, and L. Cronin*
  • 6. Electrical resistivity of individual molecular-assembly nanowires of amphiphilic bis-tetrathiafulvalene macrocycle/2,3,5,6-tetrafluoro- 7,7,8,8-tetracyano-p-quinodimethane charge transfer complex characterized by point-contact current-imaging atomic force microscopy
    Appl. Phys. Lett. 2008, 93, 1731021-17310213.

    R. Tsunashima, Y. Noda, Y. Tatewaki, S.-I. Noro, T. Akutagawa, T. Nakamura,* T. Matsumoto, T. Kawai
  • 5. Fullerene Nanowires: Self-Assembly Structures of a Low-Molecular-Weight Organogelator Fabricated by the Langmuir-Blodgett Method
    Chem. -Eur. J., 2008, 14, 8169-8170

    R. Tsunashima, S.-i. Noro, T. Akutagawa, T. Nakamura,* H. Kawakami, K. Toma
  • 4. Molecular-Assembly of Amphiphilic Gigantic {Mo154}-Ring: (Dimethyldioctadecylammoni um)20 [Mo154O462H+8(H2O)90]
    Langmuir, 2008, 24, 231-238

    T. Akutagawa, R. Jin, R. Tsunashima, S.-i. Noro, L. Cronin, T. Nakamura*
  • 3. Langmuir-Blodgett Films Constructed by Amphiphilic bis-TTF Annulated Macrocycle-2,3,5,6-Tetrafluoro-7,7,8,8-tetracyano-p-quinodimethane Charge Transfer Complex and Gold Nanoparticles
    J. Phys. Chem. C, 2007, 111, 18871-18877(cover picture)

    Y. Tatewaki, Y. Noda, T. Akutagawa, R. Tsunashima, S.-i. Noro, T. Nakamura, H. Hasegawa, S. Mashiko and J. Becher
  • 2. One-Dimensional Array of Au Nanoparticles Fixed on Nanofibers of Organogelators by the Langmuir-Blodgett Method
    J. Phys. Chem. C, 2007, 111, 901-907.

    R. Tsunashima, S.-i. Noro, T. Akutagawa, T. Nakamura,* T. Karasawa, H. Kawakami, and K. Toma
  • 1. Synthesis, Isolation, and Structural Characterization of C4h Isomer of Metal(1,2-naphthalocyanine) and Its One-Dimensional Conductor of Axially Substituted Species
    Inorg. Chem., 2006, 45, 4170-4176

    E. H. Gacho, H. Imai, R. Tsunashima, T, Naito, T. Inabe* and N. Kobayashi
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