著書

3.	“Gel-Electrophoretic Chromatography of Polyoxometalate Clusters in Aqueous Solution” R. Tsunashima* Springer, Polyoxometalate-Based Assemblies and Functional Materials Editor: Yu-Fei Song (2018) LINK
2.	“分子かクラスターか？－分子性クラスターの電子材料への展開” 綱島亮 化学同人『化学』、Vol. 70、No. 9、70-71 (2015)
1.	“POM-based Molecular and Composite Materials toward Electronic Applications” R. Tsunashima Nova Science publishers, Trends in Polyoxometalates Research, Editors: L. Ruhlmann and D. Schaming (2015).

Publications (学術論文)

37. Ferroelectric Behavior of a Hexamethylenetetramine‐Based Molecular Perovskite Structure

Angew. Chem. Int. Ed., 2019, accepted.

LINK

37. Synthesis, Structure, and Electrochemical Properties of [Na(SO3)2(RPO3)4MoV4MoVI14O49]5− (R = propyl or t-butyl)

Bull. Chem. Soc. Jpn., 2019, accepted.

Masaru Fujibayashi, Misaki Shiga, Ryo Tsunashima*, Takayoshi Nakamura

36. Structural Phase Transition Behavior Observed for a Single Crystal of the Tetrabutylammonium Salt of a Mo18 Polyoxometalate

Eur. J. Inorg. Chem., 2018, 492-495.

Hirofumi Oki, Misaki Shiga, Ippei Nakamura, Kazuki Nishida, Katsuya Ichihashi, Sadafumi Nishihara, Katsuya Inoue, Tomoyuki Akutagawa, and Ryo Tsunashima*



35. Giant Hysteretic Single-Molecule Electric Polarisation Switching above Room Temperature

Angew. Chem. Int. Ed., 2018, 57, 13429-13432. (Hot Article)

C. Kato, R. Machida, R. Maruyama, R. Tsunashima, X.-M. Ren, M. Kurmoo, K. Inoue, and S. Nishihara*

34.Chemo-chromism in an orthogonal dabco-based Co(II) network assembled by methanol-coordination and hydrogen bond formation

Dalton Trans., 2018, 47, 7656-7662. (Back Cover)

Misaki Shiga, Shogo Kawaguchi, Masaru Fujibayashi, Sadafumi Nishihara, Katsuya Inoue, Tomoyuki Akutagawa, Shin-ichiro Noro, Takayoshi Nakamura and Ryo Tsunashima*

LINK

33. Inter-cluster distance dependence of electrical properties in single crystals of a mixed-valence polyoxometalate

Dalton Trans., 2017, 46, 12619

Ryo Tsunashima,* Ippei Nakamura, Rika Oue, Seiya Koga, Hirofumi Oki, Shin-ichiro Noro, Takayoshi Nakamura and Tomoyuki Akutagawa

32. A dielectric anomaly observed for doubly reduced
mixed-valence polyoxometalate

Chem. Comm., 2017, 53, 6824-6827(back cover)

I. Nakamura, R. Tsunashima,* S. Nishihara, K. Inoue and T. Akutagawa

LINK





31. Synthesis, Characterization, and Structure of a Reduced Preyssler-type Polyoxometalate

Chem. Lett., 2017, 46, 602-604.

C. Kato, K. Y. Maryunina, K. Inoue,* S. Yamaguchi, H. Miyaoka, A. Hayashi, M. Sadakane, R. Tsunashima, and S. Nishihara*



30．Solid-state structure and electronic states of hydrogen-bonded dimer of pyridyl-substituted tetrathiafulvalene salted with PF6−

RSC Adv., 2017, 7, 6236-6241

Tomoaki Kanetou, Ryo Tsunashima*, Norihisa Hoshino and Tomoyuki Akutagawa
DOI: 10.1039/C6RA27814K

LINK





29．Solvent Triggered Transition of Electrical Conductivity of Polyoxomet-alate-Based Hybrid with Ni-Pyridyl-Tetrathiafulvalene

Current Inorganic Chemistry, 2016, 7

Yusuke Baba, Ryo Tsunashima*, Norihisa Hoshino, Tomoyuki Akutagawa, Shin-Ichiro Noro and Takayoshi Nakamura

LINK



28．Exploring the solvent mediated assembly and redox activity of a POM–organic hybrid [Na(SO3)2(PhPO3)4MoV4MoVI14O49]5−

New J. Chem., 2016, 40, 8488-8492

Masaru Fujibayashi, Yu-Fei Song, Leroy Cronin and Ryo Tsunashima*

DOI: 10.1039/C6NJ01774F

LINK





27．Synthesis and acid–base properties of a proton-bridged biaryl compound based on pyridylazulene

New J. Chem., 2015, 39, 9079-9085.
(Cover picture)

K. Ninomiya, Y, Harada, T. Kanetou, Y. Suenaga, T. Murafuji* and R. Tsunashima*
DOI: 10.1039/C5NJ01651G

26． Large in-plane/out-of-plane anisotropic conduction in PEDOT-based hybrid films: Lamellar assemblies structured by mono-layered nano-sheets

J. Mater. Chem. C, 2015, 3, 7153-7158.

S. Fujii, Y. Suzuki, J. Kawamata* and R. Tsunashima*

DOI: 10.1039/C5TC01238D




25. Investigating the Formation of “Molybdenum Blues” with Gel Electrophoresis and Mass Spectrometry

J. Am. Chem. Soc. 2015, 137, 6524-6530

I. Nakamura, H. N. Miras, A. Fujiwara, M. Fujibayashi, Y.-F. Song, L. Cronin,* and R. Tsunashima*
DOI: 10.1021/ja512758j


24. Electrical Network of Single-Crystalline Metal Oxide Nanoclusters Wired by π-Molecules

Angew. Chem. Int. Ed., 2014, 42, 11228-11231
(inside back cover)

R. Tsunashima,* Y. Iwamoto, Y. Baba, C. Kato, K. Ichihashi, S. Nishihara, K. Inoue, K. Ishiguro, Y.-F. Song, T. Akutagawa

23. Concentration Dependent Stability of Fullerene-shaped Metal-oxide Nanocluster {Mo132} in Aqueous Solution

Sci. Adv. Mater., 2014, 6, 1389-1393

T. Matsumoto, I. Nakamura, K. Ishiguro, R. Tsunashima*

22. Recent advances on polyoxometalates intercalated layered double hydroxides: From synthetic approaches to functional material applications

Coord. Chem. Rev., 2014, 258-259, 58-71

S.Omwoma, W. Chen, R. Tsunashima, Y.-F. Song*

21. Heterocyclic bismuth carboxylates based on a diphenyl sulfone scaffold: Synthesis and antifungal activity against Saccharomyces cerevisiae

Eur. J. Med. Chem., 2013, 63, 531-535

T. Murafuji,* K. Kitagawa, D. Yoshimatsu, K. Kondo, K. Ishiguro, R. Tsunashima, I. Miyakawa, Y. Mikata

20. Quick and selective synthesis of Li6[a-P2W18O62]?28H2O soluble in various organic solvents

Dalton. Trans., 2013, 42, 11363-11366

C. Kato, S. Nishihara,* R. Tsunashima, Y. Tatewaki, S. Okada, X.-M. Ren, K. Inoue,* D.-L. Long and  L. Cronin

19. Electrospun Self-Supporting Nanocomposite Films of Na9[EuW10O36]・32H2O/PAN as pH-Modulated Luminescent Switch

Ind. Eng. Chem. Res, 2013, 52, 2598-2603

X.Wang, J. Wang, R. Tsunashima, K. Pan,* B. Cao, and Y.-F. Song*

18. Color-Tunable Luminescent Films Based on the Hybrid Assemblies of [EuW10O36]9-, Bis(N-methylacridinium) Nitrate, and Layered Double Hydroxide

Eur. J. Inorg. Chem, 2013, 9, 1475-1480.

Z. Han. Y. Guo, R. Tsunashima, Y.-F. Song*

17. Recent advances on polyoxometalates-based molecular and composite materials
Chem. Soc. Rev., 2012, 41, 7384-7402.　(cover picture)

Y. F. Song* and R. Tsunashima*

16. Incorporation of Cationic Electron Donor of Ni-pyridyl-tetrathiafulvalene with Anionic Electron Acceptor of Polyoxometalate

Dalton. Trans., 2012, 41, 10060-10064

R. Tsunashima,* T. Matsumoto, N. Hoshino, W. Niiho, M. Kimura, K. Kondo, Y. Suyama, Y. Nishioka, J. Kawamata, S.-i. Noro, T.Nakamura, T. Akutagawa, K. Ishiguro*

15. Exploring the mobility of nanoscale polyoxometalates using gel electrophoresis

Chem. Sci., 2012, 3, 343-348 (cover picture)

R. Tsunashima, C. Richmond and L. Cronin*

14. Insertion of Benzyne into a Bi-S Bond: A New Synthetic Route to ortho-Functionalized Bismuthanes and Its Application to the Synthesis of Dibenzothiophene

Organometallics, 2011, 30, 4532-4538

J. Chen, T. Murafuji,* R. Tsunashima

13. Hydrogen-bonded Assemblies of Two-Electron Reduced Mixed-Valence [XMo12O40] (X = P and Si) with p-Phenylenediamines

Inorg. Chem., 2011, 50, 6711-6718

T. Akutagawa,* F. Kudo, R. Tsunashima, S.-i. Noro, L. Cronin,* T. Nakamura*

12. Exploring the thermochromism of sulfite-embedded polyoxometalate capsules

Phys. Chem. Chem. Phys., 2011, 13, 7295-7297

R. Tsunashima, D.-L. Long, T. Endo, S.-i. Noro, T. Akutagawa, T. Nakamura, R. Q. Cabrera, P. F. McMillan, P. Kogerler, L. Cronin*

11. Polyoxometalates: Building Blocks for Functional Nanoscale Systems

Angew. Chem. Int. Ed., 2010, 49, 1736-1758
(review paper)

D.-L. Long, R. Tsunashima, L. Cronin*

10. The Construction of High Nuclearity Isopolyoxoniobates With Pentagonal Building Blocks:  [HNb27O76]16- and [H10Nb31O93(CO3)]23-

Angew. Chem. Int. Ed., 2010, 49, 113-116

R. Tsunashima, D.-L. Long, H. N. Miras, D. Gabb, C. P. Pradeep, L. Cronin*

9. Adsorption and Catalytic Properties of the Inner 'Nanospace' of a Gigantic Ring-Shaped Polyoxometalate Cluster

Angew. Chem. Int. Ed., 2009, 48, 8703-8706

S. Noro,* R. Tsunashima, Y. Kamiya, K. Uemura, H. Kita, L. Cronin, T. Akutagawa, T. Nakamura*

8. Conductive Nanoscopic Fibrous Assemblies Containing Helical Tetrathiafulvalene Stacks

Chem. Asian J, 2009, 4, 1474-1479

Y. Tatewaki, T. Hatanaka, R. Tsunashima, T. Nakamura, M. Kimura, H. Shirai

7. Supramolecular Silver Polyoxometalate Architectures Direct the Growth of Composite Semiconducting Nanostructures

Angew. Chem. Int. Ed., 2009, 48, 6490-6493.

C. Streb, R. Tsunashima, D. A. MacLaren, T. McGlone, T. Akutagawa, T. Nakamura, A. Scandurra, B. Pignataro, N. Gadegaard, and L. Cronin*

6. Electrical resistivity of individual molecular-assembly nanowires of amphiphilic bis-tetrathiafulvalene macrocycle/2,3,5,6-tetrafluoro- 7,7,8,8-tetracyano-p-quinodimethane charge transfer complex characterized by point-contact current-imaging atomic force microscopy

Appl. Phys. Lett. 2008, 93, 1731021-17310213.

R. Tsunashima, Y. Noda, Y. Tatewaki, S.-I. Noro, T. Akutagawa, T. Nakamura,* T. Matsumoto, T. Kawai

5. Fullerene Nanowires: Self-Assembly Structures of a Low-Molecular-Weight Organogelator Fabricated by the Langmuir-Blodgett Method

Chem. -Eur. J., 2008, 14, 8169-8170

R. Tsunashima, S.-i. Noro, T. Akutagawa, T. Nakamura,* H. Kawakami, K. Toma

4. Molecular-Assembly of Amphiphilic Gigantic {Mo154}-Ring: (Dimethyldioctadecylammoni um)20 [Mo154O462H+8(H2O)90]

Langmuir, 2008, 24, 231-238

T. Akutagawa, R. Jin, R. Tsunashima, S.-i. Noro, L. Cronin, T. Nakamura*

3. Langmuir-Blodgett Films Constructed by Amphiphilic bis-TTF Annulated Macrocycle-2,3,5,6-Tetrafluoro-7,7,8,8-tetracyano-p-quinodimethane Charge Transfer Complex and Gold Nanoparticles

J. Phys. Chem. C, 2007, 111, 18871-18877
(cover picture)

Y. Tatewaki, Y. Noda, T. Akutagawa, R. Tsunashima, S.-i. Noro, T. Nakamura, H. Hasegawa, S. Mashiko and J. Becher

2. One-Dimensional Array of Au Nanoparticles Fixed on Nanofibers of Organogelators by the Langmuir-Blodgett Method

J. Phys. Chem. C, 2007, 111, 901-907.

R. Tsunashima, S.-i. Noro, T. Akutagawa, T. Nakamura,* T. Karasawa, H. Kawakami, and K. Toma

1. Synthesis, Isolation, and Structural Characterization of C4h Isomer of Metal(1,2-naphthalocyanine) and Its One-Dimensional Conductor of Axially Substituted Species

Inorg. Chem., 2006, 45, 4170-4176

E. H. Gacho, H. Imai, R. Tsunashima, T, Naito, T. Inabe* and N. Kobayashi